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The definition of Quillen bifunctor at nLab (and everywhere else) isn't the most natural one - which to me would be a bifunctor , where are model categories, such that and are left or right Quillen functors in each entrance. Is this idea anyhow equivalent to the actual definition? If not, why is the definition so clouded?
No. The definition is constructed so that the motivating examples satisfy the definition!
And so as to make it more useful.
ok, makes sense, thanks! I was wondering because iirc is left Quillen
It's not left Quillen unless is cofibrant, because a left Quillen functor has to preserve cofibrant objects but . (I'm assuming you're using the standard model structure on Top, in which not every object is cofibrant.)