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The [[Thomason model structure]] is a model structure on that presents the -category of CW complexes, or -groupoids. The weak equivalences of this model structure are the functors that induce a weak equivalence of the [[Kan-Quillen model structure]] on the standard simplicial nerve of the domain and codomain. There's a Quillen equivalence of the two model structures where the right adjoint is and is the right adjoint to [[barycentric subdivision]].
According to the theory of [[test categories]] there is also a Quillen adjunction where the former is the [[category of simplices]] and the latter is . I'm rather confused about the relation between this adjunction and the former one. Does in this other adjunction have the Thomason model structure as well, or is it a different one with the same weak equivalences? (And: is that actually a thing? I don't know of any examples offhand but it doesn't seem like it should be impossible based on the theorems I know...) And is this adjunction a Quillen equivalence? It seems like for a test category it should be. Does it somehow read out to be the same Quillen equivalence as above, or is it different?
For the existence of model structures on Cat with the same weak equivalences as but different cofibrations than the Thomason model structure, there's Section 3 of
George Raptis, Homotopy theory of posets, Homology Homotopy Appl. 12 2 (2010) 211-230
https://projecteuclid.org/journals/homology-homotopy-and-applications/volume-12/issue-2/Homotopy-theory-of-posets/hha/1296223882.full
I (by no means an expert, just acquainted with some bits of Cisinski 06) am not even sure where to find a claim that is a Quillen adjunction between anything.
Cisinski does bring up the Thomason model structure (Théorème 5.2.12 in Cisinski 06), but when he talks about Cat he is often just working with a [[basic localizer]] on it (so weak equivalences but not any notion of cofibration).
For a claim that is a Quillen adjunction, see page 3 of https://www.math.uwo.ca/faculty/kapulkin/notes/test_categories.pdf toward the bottom (paragraph starting "Even though"). Now, it's not exactly specific as to what this is a Quillen adjunction between!
I think it can't be the Thomason model structure.
If were a left Quillen functor, it would have to preserve cofibrant objects.
Every simplicial set is cofibrant, but any cofibrant object in the Thomason model structure is a poset (Proposition 5.7 in Thomason).
In particular the terminal object is cofibrant in simplicial sets, but is not a poset.
Aha, good catch!
Presumably whatever it is, if the claim isn't just an error, should match with all the model structures in Cisinski 06.